Ferromagnetic Ordering and Metamagnetism in Malonate Bridged 3D Diamond-like and Honeycomb-like Networks: [Cu(mal)(DMF)]n and {[Cu(mal)(0.5pyz)]·H2O}n (mal = Malonate Dianion, DMF = N,N-dimethylformamide, pyz = Pyrazine)
Authors:
- 25 June 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 42 (16) , 4792-4794
Abstract
Two three-dimensional (3D) malonate bridged networks, [Cu(mal)(DMF)]n (1) and {[Cu(mal)(0.5pyz)]·H2O}n (2), have been synthesized in H2O−DMF solution. Compound 1 exhibits ferromagnetic ordering below 2.6 K (Tc), and 2 displays a metamagnetic behavior below 3.2 K (TN).Keywords
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