Equilibrating parent aminomercaptocarbene and CO 2 with 2-amino-2-thioxoacetic acid via heavy-atom quantum tunneling
Open Access
- 17 November 2022
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Science
- Vol. 14 (1) , 130-135
Abstract
A novel heterosubstituted carbene spontaneously binds CO 2 in a tunneling reaction under cryogenic conditions.Keywords
Funding Information
- Fonds der Chemischen Industrie (Scholarship)
- Alexander von Humboldt-Stiftung (Postdoctoral Fellowship)
- Council for Higher Education
This publication has 64 references indexed in Scilit:
- N‐Heterocyclic Carbenes as Efficient Organocatalysts for CO2 Fixation ReactionsAngewandte Chemie, 2009
- CO2 Adducts of N-Heterocyclic Carbenes: Thermal Stability and Catalytic Activity toward the Coupling of CO2 with EpoxidesThe Journal of Organic Chemistry, 2008
- Double-Proton-Transfer Processes in Dithiooxamide: UV-Induced Dithione → Dithiol Reaction and Ground-State Dithiol → Dithione TunnelingThe Journal of Physical Chemistry A, 2004
- Proton-Transfer Processes in Thiourea: UV Induced Thione → Thiol Reaction and Ground State Thiol → Thione TunnelingThe Journal of Physical Chemistry A, 2003
- UV induced proton transfer in thioacetamide: first observation of thiol form of simple thioamidePhysical Chemistry Chemical Physics, 2003
- Direct Observation of Heterogeneous Chemistry in the AtmosphereScience, 1998
- 2,3‐Dihydrothiazol‐2‐ylideneAngewandte Chemie International Edition, 1997
- Theoretical and infrared matrix isolation study of 4(3H)-pyrimidinethione and 3(2H)-pyridazinethione: tautomerism and phototautomerismThe Journal of Physical Chemistry, 1991
- Theoretical and matrix-isolation experimental study on 2(1H)-pyridinethione/2-pyridinethiolThe Journal of Physical Chemistry, 1990
- On the Mechanism of Thiamine Action. IV.1 Evidence from Studies on Model SystemsJournal of the American Chemical Society, 1958