Three-Dimensional Ordered Mesoporous Carbon Spheres Modified with Ultrafine Zinc Oxide Nanoparticles for Enhanced Microwave Absorption Properties
Open Access
- 17 February 2021
- journal article
- research article
- Published by Springer Nature in Nano-Micro Letters
- Vol. 13 (1) , 1-16
Abstract
Currently, electromagnetic radiation and interference have a significant effect on the operation of electronic devices and human health systems. Thus, developing excellent microwave absorbers have a huge significance in the material research field. Herein, a kind of ultrafine zinc oxide (ZnO) nanoparticles (NPs) supported on three-dimensional (3D) ordered mesoporous carbon spheres (ZnO/OMCS) is prepared from silica inverse opal by using phenolic resol precursor as carbon source. The prepared lightweight ZnO/OMCS nanocomposites exhibit 3D ordered carbon sphere array and highly dispersed ultrafine ZnO NPs on the mesoporous cell walls of carbon spheres. ZnO/OMCS-30 shows microwave absorbing ability with a strong absorption (− 39.3 dB at 10.4 GHz with a small thickness of 2 mm) and a broad effective absorption bandwidth (9.1 GHz). The outstanding microwave absorbing ability benefits to the well-dispersed ultrafine ZnO NPs and the 3D ordered mesoporous carbon spheres structure. This work opened up a unique way for developing lightweight and high-efficient carbon-based microwave absorbing materials.Keywords
This publication has 57 references indexed in Scilit:
- Lightweight and Flexible Graphene Foam Composites for High‐Performance Electromagnetic Interference ShieldingAdvanced Materials, 2013
- Microwave Absorption Enhancement of Porous Carbon Fibers Compared with Carbon NanofibersThe Journal of Physical Chemistry C, 2012
- Microwave Absorption Enhancement of Multifunctional Composite Microspheres with Spinel Fe3O4 Cores and Anatase TiO2 ShellsSmall, 2012
- Hierarchical Dendrite-Like Magnetic Materials of Fe3O4, γ-Fe2O3, and Fe with High Performance of Microwave AbsorptionChemistry of Materials, 2011
- Zinc Oxide/Reduced Graphene Oxide Composites and Electrochemical Capacitance Enhanced by Homogeneous Incorporation of Reduced Graphene Oxide Sheets in Zinc Oxide MatrixThe Journal of Physical Chemistry C, 2011
- The effects of temperature and frequency on the dielectric properties, electromagnetic interference shielding and microwave-absorption of short carbon fiber/silica compositesCarbon, 2010
- Microwave absorbing performances of multiwalled carbon nanotube composites with negative permeabilityApplied Physics Letters, 2007
- Microwave Absorption Enhancement and Complex Permittivity and Permeability of Fe Encapsulated within Carbon NanotubesAdvanced Materials, 2004
- Low‐Temperature Wafer‐Scale Production of ZnO Nanowire ArraysAngewandte Chemie International Edition, 2003
- Optical Properties of Inverse Opal Photonic CrystalsChemistry of Materials, 2002