Ab initio investigation of hot electron transfer in CO 2 plasmonic photocatalysis in the presence of hydroxyl adsorbate
Open Access
- 16 April 2024
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Nanoscale Horizons
- Vol. 9 (6) , 1030-1041
Abstract
Co-adsorbed hydroxyl species play a significant role in changing the energy landscape of the plasmon-mediated CO 2 reaction. These promote CO 2 activation and transfer of hot electrons in newly formed hybridized orbitals, thereby improving selectivity.Keywords
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