Co-Processing Lignocellulosic Biomass and Sewage Digestate by Hydrothermal Carbonisation: Influence of Blending on Product Quality
Open Access
Abstract
Hydrothermal carbonisation (HTC) can be integrated with anaerobic digestion (AD) for the treatment of digestate, resulting in a solid hydrochar or bio-coal and a process water, which can be recirculated back into AD to produce biogas. The properties of digestate-derived hydrochars do not lend themselves to producing high quality bio-coal and blending with lignocellulosic feedstocks can improve its properties. This study investigates the co-processing of sewage sludge (SS) digestate with three lignocellulosic biomass (grass, privet hedge, and woodchip). The calorific value of the resulting bio-coal is increased following co-processing, although feedstock interactions result in non-additive behaviour. The largest increase in calorific value was observed for co-processing with woodchip. There is evidence for non-additive partitioning of metals during co-processing resulting in only moderate improvements in ash chemistry during combustion. Co-processing also effects the composition of process waters, influencing the potential for biogas production. Experimental biomethane potential (BMP) tests indicate that grass clippings are the most suitable co-feedstock for maintaining both calorific value and biogas production. However, above 200 °C, BMP yields appear to decrease, suggesting the process water may become more inhibitory. Co-processing with wood waste and privet hedge produce the higher CV bio-coal but significantly reduced BMP.Keywords
Funding Information
- Engineering and Physical Sciences Research Council (EP/L014912/1, EP/T517860/1, EP/K014714/1)
- UK-India Education and Research Initiative (IND/CONT/GA/18-19/18)
This publication has 27 references indexed in Scilit:
- A comparative assessment of biomass ash preparation methods using X-ray fluorescence and wet chemical analysisFuel, 2016
- The use of conservation biomass feedstocks as potential bioenergy resources in the United KingdomBioresource Technology, 2016
- Fate of inorganic material during hydrothermal carbonisation of biomass: Influence of feedstock on combustion behaviour of hydrocharFuel, 2016
- Hydrothermal carbonization: Fate of inorganicsBiomass and Bioenergy, 2013
- Fuel Indexes: A Novel Method for the Evaluation of Relevant Combustion Properties of New Biomass FuelsEnergy & Fuels, 2011
- Hydrothermal carbonization of biomass residuals: a comparative review of the chemistry, processes and applications of wet and dry pyrolysisBiofuels, 2011
- Hydrothermal carbonization of biomass: A summary and discussion of chemical mechanisms for process engineeringBiofuels, Bioproducts and Biorefining, 2010
- Optimisation of the anaerobic digestion of agricultural resourcesBioresource Technology, 2008
- Prediction of heating values of biomass fuel from elemental compositionAnalytica Chimica Acta, 2005
- Relationships between lignin contents and fixed carbon contents of biomass samplesEnergy Conversion and Management, 2003