New Method for Synthesis of Substituted N-Borylated Dipeptides Based on Acetonitrile Derivative of the closo-Dodecaborate Anion
Authors:
Open Access
- 21 September 2021
- journal article
- research article
- Published by Pleiades Publishing Ltd in Russian Journal of Inorganic Chemistry
- Vol. 66 (9) , 1390-1395
Abstract
A new multistage synthesis of the N-borylated dipeptide B 12 -PheGlyOH has been proposed. The approach is based on the reaction of nucleophilic addition of amino acid derivatives to the [B 12 H 11 NCCH 3 ] – anion. The products of each stage have been characterized by multinuclear NMR spectroscopy, IR absorption spectroscopy, and ESI mass spectrometry.Keywords
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