Rhodium(III)-Catalyzed Intermolecular Direct Amination of Aromatic C–H Bonds with N-Chloroamines
Authors:
- 13 December 2011
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 14 (1) , 272-275
Abstract
A Rh(III)-catalyzed direct aromatic C–H amination is achieved using N-chloroamines as a reagent. Furthermore, we also developed a one-pot amination protocol involving in situ chlorination of the secondary amines. The catalytic amination operates at mild conditions with excellent functional group tolerance and regioselectivity.Keywords
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