The first ferroelectric templated borate: [Ni(en)2pip][B5O6(OH)4]2
Authors:
- 27 May 2010
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 39 (25) , 5772-5773
Abstract
The title compound (GDUT-4) is the first templated borate compound shown to have ferroelectric properties. Its structure consists of a metal complex and isolated polyanion. The chiral structure of the compound was induced by guest-complex cations according to host–guest symmetry through hydrogen bonds (H-bonds). The origins of ferroelectricity in GDUT-4 was shown to be dependent on proton transfer through H-bonds.Keywords
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