Synthesis of small palladium nanoparticles stabilized by bisphosphine BINAP bearing an alkyl chain and their palladium nanoparticle-catalyzed carbon–carbon coupling reactions under room-temperature
- 23 June 2006
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 31,p. 3349-3351
Abstract
A new bisphosphine ligand, C8-BINAP, and C8-BINAP-stabilized palladium nanoparticles have been prepared; C8-BINAP was found to be an effective protecting ligand for preparing and stabilizing palladium nanoparticles with very small core size and narrow size distribution and the C8-BINAP–Pd nanoparticles behave as an efficient catalyst for carbon–carbon coupling reactions at room temperature.Keywords
This publication has 21 references indexed in Scilit:
- Nanoparticles as Recyclable Catalysts: The Frontier between Homogeneous and Heterogeneous CatalysisAngewandte Chemie International Edition, 2005
- Formation of Carbon−Carbon Bonds under Catalysis by Transition-Metal NanoparticlesAccounts of Chemical Research, 2003
- A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditionsJournal of Molecular Catalysis A: Chemical, 2003
- Reduced Transition Metal Colloids: A Novel Family of Reusable Catalysts?Chemical Reviews, 2002
- Improved Synthesis of Small (dCORE≈ 1.5 nm) Phosphine-Stabilized Gold NanoparticlesJournal of the American Chemical Society, 2000
- Monolayer-Protected Cluster MoleculesAccounts of Chemical Research, 1999
- Synthesis and Characterization of Hydrophobic, Organically-Soluble Gold Nanocrystals Functionalized with Primary AminesLangmuir, 1996
- Clusters and Colloids1994
- Synthesis of thiol-derivatised gold nanoparticles in a two-phase Liquid–Liquid systemJournal of the Chemical Society, Chemical Communications, 1994
- Au55[P(C6H5)3]12CI6 — ein Goldcluster ungewöhnlicher GrößeEuropean Journal of Inorganic Chemistry, 1981