Truly Monodisperse Molecular Nanoparticles of Cerium Dioxide of 2.4 nm dimensions: A {Ce100O167} Cluster

Authors:
Publisher website
Google Scholar
Abstract
Ultra‐small nanoparticles of CeO2 obtained in molecular form, so‐called molecular nanoparticles, have been limited to date to a family whose largest member is of nuclearity Ce40 with a {Ce40O58} core atom count. Herein we report that a synthetic procedure has been developed to the cation [Ce100O149(OH)18(O2CPh)60(PhCO2H)12(H2O)20]16+, a member with a much higher Ce100 nuclearity and a {Ce100O167} core that is more akin to the smallest ceria nanoparticles. Its crystal structure reveals it to possess a 2.4 nm size and high D2d symmetry, and it has also allowed identification of core surface features including facet composition, the presence and location of Ce3+and H+ (i.e. HO−) ions, and the binding modes of the ligand monolayer of benzoate, benzoic acid, and water ligands.
Funding Information
  • National Science Foundation (CHE-1900321, CHE-1828064)

This publication has 46 references indexed in Scilit: