Desulfurizative Germylation: Synthesis and Reaction of Allyl- and Allenylgermanes

Authors:
  • HSHiroshi Sano
    Hiroshi Sano
  • YMYoshiyuki Miyazaki
    Yoshiyuki Miyazaki
  • MOMakoto Okawara
    Makoto Okawara
  • YUYoshio Ueno
    Yoshio Ueno
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Abstract
Allyl- and allenylgermanes were obtained by the reaction of allyl- or propargyl sulfur compounds with triphenylgermane in the presence of a radical initiator. Allylgermanes are as effective in the allylation of aldehydes as allylsilanes or stannanes.