Electrical conductivity and electroluminescence of a new anthracene-based metal–organic framework with π-conjugated zigzag chains

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Abstract
A new three-dimensional microporous MOF has been constructed using a highly conjugated anthracene-based ligand. The rarely occurring long-range π-stacking of the ligand in the form of a zigzag chain has been found in the MOF structure, which provides not only a new charge transport pathway with high electrical conductivity of 1.3 (±0.5) × 10−3 S cm−1 but also an electroluminescence property with an emission centred at 575 nm.
Funding Information
  • Natural Science Foundation of Jilin Province (20140101228JC)
  • National Natural Science Foundation of China (21101023)
  • National Natural Science Foundation of China (21473024)

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