Iridium‐Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A C-H Bond Activation α to the Trifluoromethyl Group
- 23 February 2009
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 48 (11) , 2047-2049
Abstract
Catalytic convenience: The use of iridium or ruthenium catalysts for CH bond activation has led to the addition reaction of trifluoromethylated compounds to alkenes (see scheme). This atom‐economical reaction occurs under neutral reaction conditions and without the formation of undesired defluorinated by‐products, even at high temperature. magnified imageKeywords
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