Facile modulation of hierarchical structures in biomass-derived carbon via metal–organic framework-mediated assembly for enhanced oxygen and carbon dioxide reduction reactions
Authors:
- Shibiao ZhangSZShibiao Zhang
- Jingai ShaoJSJingai Shao
- Xiong ZhangXZXiong Zhang
- Haiping YangHYHaiping Yang
- 1 February 2026
- journal article
- Published by Tsinghua University Press in Nano Research
- Vol. 19 (2)
Abstract
A MOF-mediated Structural Modulation of biomass-derived carbon into flower-like architectures, achieving ORR activity (0.83V vs. RHE) comparable to Pt/C and enabling uniform Ni doping for CO2 electroreduction. This design delivers >91% FECO at-1.0 V vs RHE with 84.8% stability over 48-hour operation, outperforming irregular morphologies.Keywords
This publication has 43 references indexed in Scilit:
- Efficient Preparation of Biomass‐Based Ultra‐Thin 2D Porous Carbon Materials by In Situ Template‐Activation And Its Application in Sodium Ion CapacitorsAdvanced Functional Materials, 2024
- Dual‐Engineering of Porous Structure and Carbon Edge Enables Highly Selective H2O2 ElectrosynthesisAdvanced Functional Materials, 2023
- Geometric and Electronic Engineering of Atomically Dispersed Copper‐Cobalt Diatomic Sites for Synergistic Promotion of Bifunctional Oxygen Electrocatalysis in Zinc–Air BatteriesAdvanced Materials, 2023
- Mass Production of Sulfur‐Tuned Single‐Atom Catalysts for Zn–Air BatteriesAdvanced Materials, 2023
- Mesopore‐Rich Fe–N–C Catalyst with FeN4–O–NC Single‐Atom Sites Delivers Remarkable Oxygen Reduction Reaction Performance in Alkaline MediaAdvanced Materials, 2022
- Alloying Co Species into Ordered and Interconnected Macroporous Carbon Polyhedra for Efficient Oxygen Reduction Reaction in Rechargeable Zinc–Air BatteriesAdvanced Materials, 2022
- A Freestanding 3D Heterostructure Film Stitched by MOF‐Derived Carbon Nanotube Microsphere Superstructure and Reduced Graphene Oxide Sheets: A Superior Multifunctional Electrode for Overall Water Splitting and Zn–Air BatteriesAdvanced Materials, 2020
- Hierarchically Porous Carbon Plates Derived from Wood as Bifunctional ORR/OER ElectrodesAdvanced Materials, 2019
- Alloy Nanocatalysts for the Electrochemical Oxygen Reduction (ORR) and the Direct Electrochemical Carbon Dioxide Reduction Reaction (CO2RR)Advanced Materials, 2018
- A High‐Performance, Low‐Tortuosity Wood‐Carbon Monolith ReactorAdvanced Materials, 2016