A high-spin nickel( ii ) borohydride complex in dehalogenation
Authors:
- 23 November 2015
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Inorganic Chemistry Frontiers
- Vol. 3 (1) , 157-163
Abstract
A mononuclear high-spin (η 2 -BH 4 ) nickel( ii ) complex bearing a macrocyclic tridentate N-donor ligand was prepared and its reactivity was investigated in dehalogenation reactions.Keywords
Funding Information
- Ministry of Oceans and Fisheries (Marine Biotechnology Program 20150220)
- Ministry of Science, ICT and Future Planning (DGIST R&D Program 15-BD-0403 & 15-HRLA-02, KCRC 20)
- National Research Foundation of Korea (2014R1A1A2056051)
This publication has 32 references indexed in Scilit:
- Nickel macrocycles with complex hydrides—new avenues for hydrogen storage researchEnergy & Environmental Science, 2010
- Nickel-based Enzyme SystemsJournal of Biological Chemistry, 2009
- Occurrence, Classification, and Biological Function of Hydrogenases: An OverviewChemical Reviews, 2007
- Electronic Structure of Four-Coordinate C3v Nickel(II) Scorpionate Complexes: Investigation by High-Frequency and -Field Electron Paramagnetic Resonance and Electronic Absorption SpectroscopiesInorganic Chemistry, 2006
- A Stable Monomeric Nickel BorohydrideInorganic Chemistry, 2003
- From ultrasoft pseudopotentials to the projector augmented-wave methodPhysical Review B, 1999
- Chapter 28. Bioinorganic chemistryAnnual Reports Section "A" (Inorganic Chemistry), 1997
- Projector augmented-wave methodPhysical Review B, 1994
- Probing the influence of local coordination environment on ligand binding in nickel hydrogenase model complexesInorganic Chemistry, 1993
- Evidence that the heterodisulfide of coenzyme M and 7-mercaptoheptanoylthreonine phosphate is a product of the methylreductase reaction in MethanobacteriumBiochemical and Biophysical Research Communications, 1987