Microscale mechanical property variations of Al-substituted LLZO: insights from compression testing and molecular dynamics simulations

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Abstract
An organophosphine-controlled diversity-oriented synthesis of chromone inden-1-one-fused cyclopentadienylides and C-acylated 2-((chromone-3-yl)methylene)-indandiones is reported. Key attributes of the methodology are the in situ generation of an allylic P-ylide and subsequent regio- and chemoselective intramolecular cyclization reactions that preferentially result in the aforementioned chromone adducts.
Funding Information
  • National Science Foundation (2152561)
  • National Science Foundation (2152562)
  • U.S. Department of Energy (DE-AC02-05CH11231)

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