From cyclic diaryl λ 3 -bromanes/chloranes to polyfuntionalized biarylsilanes via aryne σ-bonds
Open Access
- 1 January 2026
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Science
Abstract
The synthesis of biaryl-2′-halo-2-silane derivatives via aryne insertion into the N–Si σ-bond of aminosilanes, followed by cyclization to yield diverse silacycles is described.Keywords
Funding Information
- Université de Strasbourg
- European Commission (949804)
- Centre National de la Recherche Scientifique
- Université de Haute-Alsace
This publication has 64 references indexed in Scilit:
- Organosilicon Molecules with Medicinal ApplicationsJournal of Medicinal Chemistry, 2012
- Construction of Benzosiloles, Six- and Eight-Membered Silacyclic Skeletons, via a Pd-Catalyzed Intramolecular Mizoroki–Heck Reaction of VinylsilanesOrganic Letters, 2012
- Palladium-Catalyzed Synthesis of Benzosilolo[2,3-b]indoles via Cleavage of a C(sp3)–Si Bond and Consequent Intramolecular C(sp2)–Si CouplingJournal of the American Chemical Society, 2011
- Development of an Si-Rhodamine-Based Far-Red to Near-Infrared Fluorescence Probe Selective for Hypochlorous Acid and Its Applications for Biological ImagingJournal of the American Chemical Society, 2011
- Evolution of Group 14 Rhodamines as Platforms for Near-Infrared Fluorescence Probes Utilizing Photoinduced Electron TransferACS Chemical Biology, 2011
- Development of a fluorescein analogue, TokyoMagenta, as a novel scaffold for fluorescence probes in red regionChemical Communications, 2011
- Synthesis, Characterization, and Transistor Response of Semiconducting Silole Polymers with Substantial Hole Mobility and Air Stability. Experiment and TheoryJournal of the American Chemical Society, 2008
- A design concept of long-wavelength fluorescent analogs of rhodamine dyes: replacement of oxygen with silicon atomChemical Communications, 2008
- Aminosilylation of arynes with aminosilanes: synthesis of 2-silylaniline derivativesChemical Communications, 2005
- Poly(2,7-dibenzosilole): A Blue Light Emitting PolymerJournal of the American Chemical Society, 2005