Direct‐current and alternating‐current analysis of the humidity‐sensing properties of nickel oxide doped polypyrrole encapsulated in mesoporous silica SBA‐15
- 4 November 2009
- journal article
- research article
- Published by Wiley in Journal of Applied Polymer Science
- Vol. 115 (6) , 3474-3480
Abstract
Nickel oxide (NiO) doped polypyrrole (PPy) was encapsulated in mesoporous SBA‐15. All of the synthesized samples were characterized by infrared spectroscopy, X‐ray diffraction, and scanning electron microscopy. They were investigated as humidity‐sensor materials at room temperature. The sensor showed excellent humidity sensitivity in the relative humidity range 11–95%. The humidity‐sensing properties were very much improved by encapsulation of the NiO‐doped PPy into mesoporous silica SBA‐15. Finally, the sensitivity mechanism was investigated by direct‐current (dc) and alternating‐current (ac) analysis. The dc circuit with the instantaneous polarity reversion method was designed by us to study the dc response in different humidity environments. The conductive mechanism was established through the dc and ac investigation, and the conductive particles were identified as ions and electrons. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010Keywords
This publication has 22 references indexed in Scilit:
- Humidity sensitivity of polypyrrole and polypyrrole/SBA‐15 host–guest composite materialsJournal of Applied Polymer Science, 2006
- Electrical and humidity sensing properties of polyaniline/WO3 compositesSensors and Actuators B: Chemical, 2006
- Gas and humidity response of iron oxide—Polypyrrole nanocompositesSensors and Actuators B: Chemical, 2006
- Sensing behaviors of polypyrrole sensor under humidity conditionSensors and Actuators B: Chemical, 2005
- The application of CNT/Nafion composite material to low humidity sensing measurementSensors and Actuators B: Chemical, 2005
- Humidity sensors using in situ synthesized sodium polystyrenesulfonate/ZnO nanocompositesTalanta, 2004
- Solid state electrical conductivity and humidity sensing properties of WO3–Y2O3 compositesPhysica Status Solidi (a), 2004
- Electrical and humidity sensing properties of Chromium(III) oxide–tungsten(VI) oxide compositesSensors and Actuators B: Chemical, 2003
- Intercalated polypyrrole/Na+-montmorillonite nanocomposite via an inverted emulsion pathway methodPolymer, 2003
- Humidity sensing properties of Nation and sol-gel derived SiO2/Nafion composite thin filmsSensors and Actuators B: Chemical, 1997