Synthesis of soluble N‐functionalized polysaccharide derivatives using phenyl carbonate precursor and their application as catalysts
Authors:
- 5 September 2011
- journal article
- research article
- Published by Wiley in Starch - Stärke
- Vol. 63 (12) , 780-791
Abstract
Soluble N‐functionalized basic and cationic polysaccharides have been synthesized using polysaccharide phenyl carbonate as a precursor. The products and intermediates were thoroughly characterized by conventional methods. The quaternization of amino intermediates in various conditions was studied. Moreover, the potential of basic polymers as green and selective catalysts in Knoevenagel reaction was investigated. In all cases, only one isomer was obtained.Keywords
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