Catalytic carboborations
- 17 September 2010
- journal article
- review article
- Published by Wiley in The Chemical Record
- Vol. 10 (5) , 348-358
Abstract
Transition‐metal‐catalyzed carboborations, in which organic and boryl groups are introduced concomitantly to unsaturated organic molecules, have been developed. Direct carboborations, which proceed via activation of B–C bonds of cyanoboranes and alkynylboranes, and transmetalative carboborations, in which activation of B–Cl bonds is followed by transmetalation from organotin and organozirconium reagents, are overviewed. In addition, as representative results and mechanistic considerations, the scientific background and a personal view behind the study are also described. © 2010 The Japan Chemical Journal Forum and Wiley Periodicals, Inc. Published online in Wiley InterScience (www.interscience.wiley.com)Keywords
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