Silver Complexes of Dihalogen Molecules
- 12 July 2016
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 55 (32) , 9259-9261
Abstract
The perfluorohexane‐soluble and donor‐free silver compound Ag(A) (A=Al(ORF)4; RF=C(CF3)3) prepared using a facile novel route has unprecedented capabilities to form unusual and weakly bound complexes. Here, we report on the three dihalogen–silver complexes Ag(Cl2)A, Ag(Br2)A, and Ag(I2)A derived from the soluble silver compound Ag(A) (characterized by single‐crystal/powder XRD, Raman spectra, and quantum‐mechanical calculations).Keywords
Funding Information
- European Research Council
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