The effect of flow maldistribution on conversion in a catalytic packed‐bed reactor. Part II. Experimental studies
Authors:
- 1 November 1976
- journal article
- research article
- Published by Wiley in AIChE Journal
- Vol. 22 (6) , 1027-1032
Abstract
The modeling equations formulated for a catalytic packed‐bed reactor with distributed resistance to flow have been applied to the alumina catalyzed isomerization of 1‐butene to cis‐ and trans‐2‐butene. Flow maldistribution was deliberately created in a 5.25 cm I.D. reactor by packing different radial sections with alumina particles of different size. Effluent gas composition, monitored by gas chromatography, was found to vary with radial position in a manner consistent with the modeling equations and with the reaction rate constant previously established in a microreactor.Keywords
This publication has 4 references indexed in Scilit:
- Tracer studies of acid-catalyzed reactionsJournal of Catalysis, 1967
- Studies of the hydrogen held by solids: IX. The hydroxyl groups of alumina and silica-alumina as sites for the isomerization of buteneJournal of Catalysis, 1966
- Alumina: Catalyst and Support. III.1a The Kinetics and Mechanisms of Olefin Isomerization1bJournal of the American Chemical Society, 1960
- Heats, equilibrium constants, and free energies of formation of the monoolefin hydrocarbonsJournal of Research of the National Bureau of Standards, 1946