Measurement of PVC fusion (gelation)

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Abstract
PVC fusion (gelation) occurs with melting of crystallites followed by recrystallization. This recrystallization, as it occurs at the primary particle boundary, physically ties together the structure into a three dimensional network. One way of measuring the extent of this three dimensional network structure is to measure the force required to deform the material through a zero land length capillary. We examine this test method for various molecular weight PVC compounds, with and without plasticizer, and for various degrees of grinding the product.

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