Ambient-Temperature Spin-State Switching Achieved by Protonation of the Amino Group in [Fe(H2Bpz2)2(bipy-NH2)]
- 29 July 2016
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 55 (16) , 8147-8152
Abstract
Magnetism of a complex [Fe(H2Bpz2)2(bipy-NH2)] (H2Bpz2 = dihydrobis(1-pyrazolyl)borate, bipy-NH2 = 4,4′-diamino-2,2′-bipyridine) has been altered from paramagnetic to spin-crossover (SCO) behavior, through protonation of one amino group of bipy-NH2 with CF3SO3H. Complete SCO transition, both in solid state and in solution, occurs at ambient temperature.Keywords
Funding Information
- Japan Society for the Promotion of Science (26288021)
- National Natural Science Foundation of China (21371031)
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Graduate School, Southeast University (YBPY1409)
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