A heterogeneous bio-inspired peroxide shunt for catalytic oxidation of organic molecules
Authors:
- 22 August 2020
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 56 (78) , 11593-11596
Abstract
Iron porphyrins with three different axial ligands installed atop self-assembled monolayer modified gold electrodes can oxidize C–H bonds and epoxidize alkenes efficiently using H2O2via the formation of a high-valent intermediate.Keywords
Funding Information
- Anusandhan National Research Foundation (EMR008063)
This publication has 30 references indexed in Scilit:
- Crystal Structure of H2O2-dependent Cytochrome P450SPα with Its Bound Fatty Acid SubstrateJournal of Biological Chemistry, 2011
- Gauging the Relative Oxidative Powers of Compound I, Ferric-Hydroperoxide, and the Ferric-Hydrogen Peroxide Species of Cytochrome P450 Toward C−H Hydroxylation of a Radical Clock SubstrateJournal of the American Chemical Society, 2005
- Structure and Chemistry of Cytochrome P450Chemical Reviews, 2005
- Factors Affecting the Catalytic Epoxidation of Olefins by Iron Porphyrin Complexes and H2O2 in Protic SolventsThe Journal of Organic Chemistry, 2003
- Metal-Catalyzed Epoxidations of Alkenes with Hydrogen PeroxideChemical Reviews, 2003
- Formation of Compound I in the Reaction of Native Myoglobins with Hydrogen PeroxideJournal of Biological Chemistry, 2000
- Ozone as primary oxidant in iron(III) porphyrin catalyzed hydroxylation of hydrocarbonsJournal of Molecular Catalysis A: Chemical, 1997
- Heme-Containing OxygenasesChemical Reviews, 1996
- High-yield epoxidations with hydrogen peroxide and tert-butyl hydroperoxide catalyzed by iron(III) porphyrins: heterolytic cleavage of hydroperoxidesJournal of the American Chemical Society, 1993
- Models for cytochrome P-450Journal of the American Chemical Society, 1975