Recent Advances in Acyl Suzuki Cross-Coupling
Open Access
Abstract
Acyl Suzuki cross-coupling involves the coupling of an organoboron reagent with an acyl electrophile (acyl halide, anhydride, ester, amide). This review provides a timely overview of the very important advances that have recently taken place in the acylative Suzuki cross-coupling. Particular emphasis is directed toward the type of acyl electrophiles, catalyst systems and new cross-coupling partners. This review will be of value to synthetic chemists involved in this rapidly developing field of Suzuki cross-coupling as well as those interested in using acylative Suzuki cross-coupling for the synthesis of ketones as a catalytic alternative to stoichiometric nucleophilic additions or Friedel-Crafts reactions.Keywords
Funding Information
- National Science Foundation (CHE-1650766)
This publication has 106 references indexed in Scilit:
- Metal‐Catalyzed Synthesis and Use of Thioesters: Recent DevelopmentsChemistry – A European Journal, 2018
- Selection of boron reagents for Suzuki–Miyaura couplingChemical Society Reviews, 2013
- Transmetalation in the Suzuki–Miyaura Coupling: The Fork in the TrailAngewandte Chemie International Edition, 2013
- Palladium‐Catalyzed Cross‐Coupling: A Historical Contextual Perspective to the 2010 Nobel PrizeAngewandte Chemie International Edition, 2012
- Carboxylic Acids as Substrates in Homogeneous CatalysisAngewandte Chemie International Edition, 2008
- Novel Substrates for Palladium‐Catalyzed Coupling Reactions of ArenesAngewandte Chemie International Edition, 2003
- Reaction of acyl chlorides with organometallic reagents: A banquet table of metals for ketone synthesisTetrahedron, 1999
- Palladium-Catalyzed Cross-Coupling Reactions of Organoboron CompoundsChemical Reviews, 1995
- Palladium-catalyzed acylation of organozincs and other organometallics as a convenient route to ketonesTetrahedron Letters, 1983
- Mild, selective, general method of ketone synthesis from acid chlorides and organotin compounds catalyzed by palladiumThe Journal of Organic Chemistry, 1979