Über eine neuartige Synthese von β‐Ketoallenen durch Reaktion von tertiären Acetylencarbinolen mit Vinyläthern eine ergiebige methode zur darstellung des Pseudojonons und verwandter verbindungen

Authors:
Publisher website
Google Scholar
Abstract
The novel acid‐catalysed reaction of isopropenyl ether with tertiary acetylenic carbinols to give β‐ketoallenes in high yields is described. Upon treatment with bases, these allenes readily undergo isomerization to conjugated dienones. This reaction sequence results in an economic synthesis of pseudo‐ionones and pseudo‐irones from dehydrolinalool and its homologs.

This publication has 19 references indexed in Scilit: