Facile Synthesis of Versatile and Air‐stable Cuprous Synthons of Type [Cu(NHC)(OC(H)(CF3)2)] (NHC=N‐Heterocyclic Carbene)
Authors:
- 5 January 2025
- journal article
- Published by Wiley in European Journal of Inorganic Chemistry
- Vol. 28 (7)
Abstract
A new family of Cu‐NHC complexes having general formula [Cu(NHC)(OC(H)(CF3)2)] (NHC=N‐Heterocyclic Carbene; OC(H)(CF3)2=1,1,1,3,3,3‐hexafluoroisopropanol (HFIP)) is reported. The operational simple protocol of the weak base route allows the formation of a series of new fluorinated cuprous synthons, opening the doors to new possible synthetic and catalytic pathways, as demonstrated by the hexafluoroisopropoxylation of 9‐chloroacridine using [Cu(IPr)(OC(H)(CF3)2)] (2).Keywords
Funding Information
- Narodowa Agencja Wymiany Akademickiej (BPN/BEK/2021/1/00168/U/DRAFT/00001)
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