In‐situ interfacial polymerization endows surface enrichment of -COOH groups on anion exchange membranes for efficient Cl−/SO42− separation

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Abstract
In‐situ interfacial polymerization technique is developed to prepare monovalent anion‐permselective membranes (MAPMs). The introduction of multi‐hydroxyl (OH) and cationic groups in the base membrane provide suitable routes towards the monovalent anion transport. Only trimesoyl chloride is employed to generate a crosslinked polyester layer on membrane surface. The ISIP transforms the surface of anion exchange membranes into a dense and negatively charged layer to promote the ion permselectivity. The modified membranes show a high limiting current density and low membrane resistance of 4.7 Ω cm2. The resultant membranes exhibit a high Cl− flux of 6.3 × 10−8 mol cm−2 s−1 and a high permselectivity of ~60 for Cl−/SO42−. The findings demonstrate the ISIP technique having great potentials for the fabrication of highly permselective MAPMs.
Funding Information
  • Natural Science Foundation of Anhui Province (2108085MB33)
  • Key Technologies Research and Development Program of Anhui Province (202104b11020030)
  • National Natural Science Foundation of China (52021002, U20A20127, 21878282)

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