A Terminal Fluoride Ligand Generates Axial Magnetic Anisotropy in Dysprosium Complexes
Authors:
- 16 January 2018
- journal article
- research article
- Published by Wiley in Angewandte Chemie
- Vol. 130 (7) , 1951-1956
Abstract
The first dysprosium complexes with a terminal fluoride ligand are obtained as air‐stable compounds. The strong, highly electrostatic dysprosium–fluoride bond generates a large axial crystal‐field splitting of the J=15/2 ground state, as evidenced by high‐resolution luminescence spectroscopy and correlated with the single‐molecule magnet behavior through experimental magnetic susceptibility data and ab initio calculations.Keywords
Funding Information
- H2020 Marie Skłodowska-Curie Actions (800719)
- National Science Foundation (CHE-1464841)
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