Aerobic Synthesis of Zinc Organophosphate Complexes from Elemental Zinc: Enabling Phosphoric Acid Diester-Based Catalysis for O 2 -Mediated Baeyer-Villiger Oxidation
- 21 April 2026
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Organic Chemistry Frontiers
- Vol. 13 (15) , 4509-4519
Abstract
We report the first aerobic synthesis of zinc organophosphate complexes, Zn[O 2 P(OR) 2 ] 2 , from inexpensive elemental zinc (Zn(0)) and structurally diverse phosphoric acid diesters (PADs) under ambient conditions. This mild and operationally...Keywords
Funding Information
- Japan Science and Technology Agency (JPMJSP2113)
This publication has 47 references indexed in Scilit:
- Aerobic Baeyer–Villiger Oxidation Catalyzed by a Flavin‐Containing Enzyme Mimic in WaterAngewandte Chemie International Edition, 2018
- A Solvent Switch for the Stabilization of Multiple Hemiacetals on an Inorganic Platform: Role of Supramolecular InteractionsChemistry – A European Journal, 2016
- Noncovalent Synthesis of Hierarchical Zinc Phosphates from a Single Zn4O12P4 Double‐Four‐Ring Building Block: Dimensionality Control through the Choice of Auxiliary LigandsChemistry – A European Journal, 2010
- Chiral Brønsted Acid Catalyzed Asymmetric Baeyer–Villiger Reaction of 3‐Substituted Cyclobutanones by Using Aqueous H2O2Angewandte Chemie International Edition, 2008
- An Aerobic, Organocatalytic, and Chemoselective Method for Baeyer–Villiger OxidationAngewandte Chemie International Edition, 2005
- Monooxygenase-Mediated Baeyer−Villiger OxidationsEuropean Journal of Organic Chemistry, 2002
- A proposal for the origin of stereoselectivity in enzyme catalysed Baeyer-Villiger reactionsTetrahedron: Asymmetry, 1996
- Optically Active Lactones from a Baeyer–Villiger‐Type Metal‐Catalyzed Oxidation with Molecular OxygenAngewandte Chemie International Edition, 1994
- Recherches sur la formation et la transformation des esters XV Action des acides polyphosphoriques et phosphorique sur les glycols et les hydroxy‐éthersHelvetica Chimica Acta, 1959
- Sur l′acide o‐phénylène‐cyclophosphorique et le mécanisme de sa formationHelvetica Chimica Acta, 1951