Thermodynamics and high-pressure kinetics of a fast carbon dioxide fixation reaction by a (2,6-pyridinedicarboxamidato-hydroxo)nickel( ii ) complex
Open Access
- 26 February 2014
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 43 (14) , 5274-5279
Abstract
The thermodynamics and high-pressure kinetics of the fastest CO 2 fixation reaction by a metal-bound hydroxide resulted in a clear mechanistic picture and characterization of a very compact five-coordinate transition state.Keywords
This publication has 64 references indexed in Scilit:
- Mechanistic Insight from Activation Parameters for the Reaction of a Ruthenium Hydride Complex with CO2 in Conventional Solvents and an Ionic LiquidInorganic Chemistry, 2012
- An Experimental Investigation of the Solubility of CO2 in (N,N-Dimethylmethanamide + Water)Journal of Chemical & Engineering Data, 2012
- Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reactionProceedings of the National Academy of Sciences, 2011
- Reactions of the Terminal NiII−OH Group in Substitution and Electrophilic Reactions with Carbon Dioxide and Other Substrates: Structural Definition of Binding Modes in an Intramolecular NiII···FeIIBridged SiteJournal of the American Chemical Society, 2010
- CO2 reduction on Pt electrocatalysts and its impact on H2 oxidation in CO2 containing fuel cell feed gas – A combined in situ infrared spectroscopy, mass spectrometry and fuel cell performance studyElectrochimica Acta, 2005
- Protonation and Reactivity towards Carbon Dioxide of the Mononuclear Tetrahedral Zinc and Cobalt Hydroxide Complexes, [TpBut,Me]ZnOH and [TpBut,Me]CoOH: Comparison of the Reactivity of the Metal Hydroxide Function in Synthetic Analogues of Carbonic AnhydraseJournal of the American Chemical Society, 2003
- Electrochemical conversion of carbon dioxide to methane in aqueous NaHCO3 solution at less than 273 KElectrochimica Acta, 2002
- Electrochemical reduction of carbon dioxide to ethylene with high Faradaic efficiency at a Cu electrode in CsOH/methanolElectrochimica Acta, 1999
- Bivalent, Trivalent, and Tetravalent Nickel Complexes with a Common Tridentate Deprotonated Pyridine Bis-Amide Ligand. Molecular Structures of Nickel(II) and Nickel(IV) and Redox ActivityInorganic Chemistry, 1999
- Efficient photocatalytic CO2 reduction using [Re(bpy) (CO)3{P(OEt)3}]+Journal of Photochemistry and Photobiology A: Chemistry, 1996