Palladium-Catalyzed Decarboxylation and Decarbonylation under Hydrothermal Conditions: Decarboxylative Deuteration
- 14 May 2004
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 6 (12) , 2071-2073
Abstract
Decarboxylation of free carboxylic acid was performed by Pd/C catalyst under hydrothermal water (250 °C/4 MPa). Under the hydrothermal conditions of deuterium oxide, decarbonylative deuteration was observed to give fully deuterated hydrocarbons from carboxylic acids or aldehydes.Keywords
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