Modification of the Highly Conductive PEDOT:PSS Layer for Use in Silver Nanogrid Electrodes for Flexible Inverted Polymer Solar Cells
- 20 February 2017
- journal article
- research article
- Published by American Chemical Society (ACS) in ACS Applied Materials & Interfaces
- Vol. 9 (8) , 7834-7842
Abstract
Silver nanogrid based flexible transparent electrode is recognized as the most promising alternative to ITO electrode for organic electronics, owing to its low production cost and excellent flexibility. Typically, a highly conductive thin film coating layer, such as highly conductive PEDOT:PSS (HC-PEDOT:PSS) is usually deposited onto the Ag-grid electrode to smooth the surface and to minimize the sheet resistance. In this paper, we found that inverted flexible polymer solar cells with structure of Ag-grid/HC-PEDOT:PSS/ZnO/photoactive layer/MoO3/Al generally exhibits strong S-shaped J–V curves, which could be eliminated by light-soaking treatment. Kelvin probe force microscope (KPFM) measurement proved that a large work function (WF) difference (0.70 eV) between HC-PEDOT:PSS and ZnO is the main reason for the formation of S-shape. White light soaking of the Ag-grid/HC-PEDOT:PSS gradually decreased the WF of HC-PEDOT:PSS from 5.10 to 4.60 eV, leading to a reduced WF difference between HC-PEDOT:PSS and ZnO from 0.70 to 0.38 eV. Such a WF difference decrease was believed to be the working mechanism for the light-soaking effect in this flexible device. Based on this finding, the HC-PEDOT:PSS solution was then modified by doping with polyethylenimine (PEI) and aqueous ammonia. The modified PEDOT:PSS film is characteristic of adjusting WF through varying PEI doping concentrations. By using such a modified PEDOT:PSS layer, light-soaking-free flexible inverted polymer solar cell with a power conversion efficiency of 6.58% was achieved for PTB7-Th:PC71BM cells. The current work provides a useful guideline for interfacial modification for Ag-grid based flexible electrode.Keywords
Funding Information
- Ministry of Science and Technology of the People's Republic of China (2016YFA0200700)
- Natural Science Foundation of Jiangsu Province (BE2015071, BK20130346)
- National Natural Science Foundation of China (61306073)
- Chinese Academy of Sciences (XDA09020201)
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