Functional Silsesquioxanes—Tailoring Hydrophobicity and Anti-Ice Properties of Polylactide in 3D Printing Applications

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Abstract
To explore the tailoring of hydrophobicity in 3D-printed polylactide (PLA) composites for advanced applications using additive manufacturing (AM), this study focuses on the use of Fused Deposition Modeling (FDM) 3D printing. PLA, a material derived from renewable sources, is favored for its eco-friendliness and user accessibility. Nonetheless, PLA’s inherent hydrophilic properties result in moisture absorption, negatively affecting its performance. This research aims to modify PLA with organosilicon compounds to enhance its hydrophobic and anti-icing properties. Incorporating fluorinated siloxane derivatives led to significant increases in water contact angles by up to 39%, signifying successful hydrophobic modification. Mechanical testing demonstrated that the addition of organosilicon additives did not compromise the tensile strength of PLA and, in some instances, improved impact resistance, especially with the use of OSS-4OFP:2HEX:2TMOS, which resulted in an increase in the tensile strength value of 25% and increased impact strength by 20% compared to neat PLA. Differential scanning calorimetry (DSC) analysis indicated that the modified PLA exhibited reduced cold crystallization temperatures without altering the glass transition or melting temperatures. These results suggest that organosilicon-modified PLA has the potential to expand the material’s application in producing moisture and ice-resistant 3D-printed prototypes for various industrial uses, thereby facilitating the creation of more durable and versatile 3D-printed components.
Funding Information
  • Narodowe Centrum Badań i Rozwoju (LIDER/01/0001/L-10/18/NCBR/2019, 21/529535/SPUB/SP/2022, RPWP.01.01.00-30-0004/18, POIR.04.02.00-00-D003/20-00)
  • Ministerstwo Edukacji i Nauki (LIDER/01/0001/L-10/18/NCBR/2019, 21/529535/SPUB/SP/2022, RPWP.01.01.00-30-0004/18, POIR.04.02.00-00-D003/20-00)
  • European Funds (LIDER/01/0001/L-10/18/NCBR/2019, 21/529535/SPUB/SP/2022, RPWP.01.01.00-30-0004/18, POIR.04.02.00-00-D003/20-00)
  • The Smart Growth Operational Programme (LIDER/01/0001/L-10/18/NCBR/2019, 21/529535/SPUB/SP/2022, RPWP.01.01.00-30-0004/18, POIR.04.02.00-00-D003/20-00)

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