A Comparative Study on Recent Developments for Individual Rare Earth Elements Separation
Open Access
Abstract
Facilitating the demands of modern society, namely, smartphones, televisions, electric vehicles, and high-stability aircraft structures, requires low-cost and high-performance materials and a corresponding change in the approach needed to design them. Rare earth elements (REEs) play a significant role in achieving these objectives by adding small amounts of these elements to alloys, thereby enhancing material properties. Despite being more abundant than precious metals, the 17 REEs exhibit subtle variations in their chemical and physical characteristics. Thus, their separation is still crucial for industrial applications. There is a corresponding need to develop more effective and efficient separation methods. Adding to the separation challenge is the complexity of the sources of REEs and related materials. Thus, large-scale production of REE materials is difficult. Current REE processing techniques can be categorized into pre-treatment, beneficiation, separation, and refining. Researchers have developed various technologies encompassing chemical, physical, and biological methods, focusing on economic and environmental considerations. However, not all these approaches can be scaled up for mass production. This article focuses on feasible strategies such as precipitation and crystallization, oxidation and reduction, ion exchange, adsorption, solvent extraction, and membrane separation. Further research into these traditional and modern methods can potentially revolutionize the separation dynamics of REEs.Keywords
This publication has 96 references indexed in Scilit:
- Homogeneous Liquid–Liquid Extraction of Rare Earths with the Betaine—Betainium Bis(trifluoromethylsulfonyl)imide Ionic Liquid SystemInternational Journal of Molecular Sciences, 2013
- The Chemistry and Applications of Metal-Organic FrameworksScience, 2013
- Introduction to Metal–Organic FrameworksChemical Reviews, 2012
- Density and viscosity of several pure and water-saturated ionic liquidsGreen Chemistry, 2005
- Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cationGreen Chemistry, 2001
- Influence of chloride, water, and organic solvents on the physical properties of ionic liquidsPure and Applied Chemistry, 2000
- Chemical Separations with Liquid Membranes: An Overview1996
- Thermodynamics of solvation of ions. Part 5.—Gibbs free energy of hydration at 298.15 KJournal of the Chemical Society, Faraday Transactions, 1991
- The use of rare earths in ceramicsJournal of the Less Common Metals, 1985
- Ion Exchange as a Separation Method. VI. Column Studies of the Relative Efficiencies of Various Complexing Agents for the Separation of Lighter Rare EarthsJournal of the American Chemical Society, 1953