A 31P NMR Investigation of the CoPi Water‐Oxidation Catalyst
- 17 July 2012
- journal article
- research article
- Published by Wiley in Chemistry – A European Journal
- Vol. 18 (34) , 10476-10479
Abstract
Beneath the sheets: 31P NMR data suggests that phosphates are liberated freely in the interlayer of a cobalt-hydroxide water-oxidation catalyst. The cobalt-hydroxide sheets (see figure) are separated by an interlayer region with water, counterions and phosphate, which help to shuttle protons as the layer develops charge.Keywords
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