Asymmetric Simmons−Smith Cyclopropanation of Unfunctionalized Olefins
Authors:
- 18 October 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (45) , 13632-13633
Abstract
This paper describes a promising asymmetric cyclopropanation system for unfunctionalized olefins using readily available dipeptide N-Boc-l-Val-l-Pro-OMe as ligand.Keywords
This publication has 12 references indexed in Scilit:
- A catalytic enantioselective reaction using a C2-symmetric disulfonamide as a chiral ligand: cyclopropanation of allylic alcohols by the Et2Zn-CH2I2-disulfonamide systemTetrahedron Letters, 1992
- Carbohydrates as chiral auxiliaries: asymmetric cyclopropanation reaction of acyclic olefinsJournal of the American Chemical Society, 1991
- Asymmetric cyclopropanation of 1-alkenylboronic esters and its application to the synthesis of optically active cyclopropanolsThe Journal of Organic Chemistry, 1990
- Use of cyclopropanes and their derivatives in organic synthesisChemical Reviews, 1989
- The Cyclopropyl Group in Studies of Enzyme Mechanism and InhibitionAngewandte Chemie International Edition, 1988
- Diastereo-differentiating simmons-smith reaction using 2,4-pentanediol as a chiral auxiliaryTetrahedron Letters, 1988
- An asymmetric Simmons-Smith reactionJournal of the American Chemical Society, 1985
- Partial asymmetric synthesis in the Simmons-Smith reaction. IIThe Journal of Organic Chemistry, 1968
- A stereospecific synthesis of cyclopropane derivatives from olefinsTetrahedron Letters, 1968
- A NEW SYNTHESIS OF CYCLOPROPANES FROM OLEFINSJournal of the American Chemical Society, 1958