Numerical Simulation of Gaseous Detonation Performance and Wall Reflection Effect of Acetylene-Rich Fuel
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Open Access
Abstract
The efficient utilization of energy in rich fuel detonation processes and the effective control method of soot are important topics in combustion research. In this paper, we numerically study the detonation wave behavior of acetylene–air systems in rich fuel condition by using a reduced reaction mechanism. The non-stiff terms of the governing equations are solved explicitly using the gas kinetic scheme, and the stiff terms are solved implicitly. Our results show that the acetylene pyrolysis is the dominant reaction process. The oxidation reaction is exploited to initiate the reaction induction process, providing the required energy to overcome the potential energy barrier. The secondary detonation structure is due to the stable interaction of the transverse waves and the combined action of the vinyl reaction system, thus effectively improve the energy release rate and providing a powerful solution for the fuel-rich high-energy release of advanced heat engines. The area of the unreacted pocket increases with the acetylene concentration, resulting in an irregular wave-front and detonation cell. The reflected shock wave impacting on the wall induces the secondary reaction of the detonation products. The concentration of polycyclic aromatic hydrocarbons decreases significantly and regenerates near the wall. Our approach provides an effective tool for controlling detonation soot and the preparation of carbon particles.Keywords
Funding Information
- National Natural Science Foundation of China (50776045, 51576098)
This publication has 39 references indexed in Scilit:
- Experimental and kinetic studies of acetylene flames at elevated pressuresProceedings of the Combustion Institute, 2015
- Comprehensive H2/O2 kinetic model for high‐pressure combustionInternational Journal of Chemical Kinetics, 2011
- Carbon condensation wave in C3O2 and C2H2 initiated by a shock waveProceedings of the Combustion Institute, 2011
- Formation of a detonation wave in the process of chemical condensation of carbon nanoparticlesJournal of Engineering Physics and Thermophysics, 2010
- Detailed chemical kinetic modeling of pyrolysis of ethylene, acetylene, and propylene at 1073–1373 K with a plug‐flow reactor modelInternational Journal of Chemical Kinetics, 2008
- Simulation numérique des détonations à double structure cellulaireComptes Rendus Mécanique, 2006
- A Gas-Kinetic Scheme for Multimaterial Flows and Its Application in Chemical ReactionsJournal of Computational Physics, 2000
- Towards the ultimate conservative difference scheme. V. A second-order sequel to Godunov's methodJournal of Computational Physics, 1979
- Role of soot in acetylene detonationCombustion, Explosion, and Shock Waves, 1977
- Gaseous Detonations. IV. The Acetylene-Oxygen MixturesThe Journal of Chemical Physics, 1952