Multi-dimensional inverse Laplace spectroscopy in the NMR of porous media
Authors:
- Petrik GalvosasPGPetrik Galvosas
- 1 March 2010
- journal article
- review article
- Published by MathDoc/Centre Mersenne in Comptes Rendus. Physique
- Vol. 11 (2) , 172-180
Abstract
Multi-dimensional NMR methods based on Inverse Laplace Transformations (ILT) may be used to examine the behavior of liquid state molecules in a porous matrix. The ILT is particularly useful when the signal is characterized by multi-exponential decay, for example in spin relaxation or in the dephasing of the NMR spin echo signal associated with molecular diffusion under the influence of pulsed magnetic or internal field gradients. Both correlation and exchange experiments are possible, the latter providing insight regarding the migration of molecules between regions characterized by different local dynamics.Keywords
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