Statistical distribution of binary ligands within rhodium–organic octahedra tunes microporosity in their assemblies

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Abstract
Structure–porosity relationships for metal–organic polyhedra (MOPs) are hardly investigated because of the difficulty in structural characterization. Here, we show a mixed ligand strategy to statistically distribute two distinct carbazole-type ligands within rhodium-based octahedral MOPs, leading to systematical tuning of the microporosity in the resulting amorphous solids.
Funding Information
  • Japan Society for the Promotion of Science (22KJ1784, 23K13762, 23H00298)