Molecular structure and dielectric anisotropy of ethanol–water mixtures within a heterogeneous graphene/silica interface
Authors:
- 30 April 2026
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Nanoscale
- Vol. 18 (23) , 12251-12265
Abstract
This work reveals how hybrid graphene/silica interfaces modulate the structure and dielectric behavior of confined ethanol–water mixtures. Interfacial asymmetry induces demixing and directional polarization, leading to dielectric anisotropy.Keywords
Funding Information
- National Natural Science Foundation of China (22378185)
This publication has 93 references indexed in Scilit:
- Interfacial dynamics of graphene in water environments: Role of wettability and surface chargesApplied Surface Science, 2025
- Simulation and analysis of slip flow of water at hydrophobic silica surfaces of nanometer slit poresColloids and Surfaces A: Physicochemical and Engineering Aspects, 2021
- Molecular simulation study of dielectric constants of pure fluids and mixturesFluid Phase Equilibria, 2020
- Insights on the mechanism of water-alcohol separation in multilayer graphene oxide membranes: Entropic versus enthalpic factorsCarbon, 2018
- Hydrogen bonding in water nanoconfined between graphene surfaces: a molecular dynamics simulation studyJournal of Nanoparticle Research, 2013
- Methane and carbon dioxide adsorption in clay-like slit pores by Monte Carlo simulationsFluid Phase Equilibria, 2013
- Ethanol inhibition of recombinant NMDA receptors is not altered by coexpression of CaMKII-α or CaMKII-βAlcohol, 2008
- Characterization of Heterogeneous Interaction Behavior in Ternary Mixtures by a Dielectric Analysis: Equi-Molar H–bonded Binary Polar Mixtures in Aqueous SolutionsJournal of Solution Chemistry, 2006
- New modeling and experimental framework to characterize hindered and restricted water diffusion in brain white matterMagnetic Resonance in Medicine, 2004
- Fast Parallel Algorithms for Short-Range Molecular DynamicsJournal of Computational Physics, 1995