Motion in solid organotin(IV) coordination polymers: a two-dimensional exchange magic angle spinning 13C NMR study

Authors:

DADavid C. Apperley
David C. Apperley
NDNicola A. Davies
Nicola A. Davies
RHRobin K. Harris
Robin K. Harris
SEStefan Eller
Stefan Eller
PSPeter Schwarz
Peter Schwarz
RFR. Dieter Fischer
R. Dieter Fischer

1 January 1992

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 10,p. 740-741
DOI:10.1039/c39920000740

Abstract

Solid-state ¹³C CP MAS NMR studies of compounds [(Me₃Sn)₄M(CN)₆]_∞ with M = Fe, Ru and Os, using variable temperature, show that the trigonal bipyramidal arrangements at Sn are undergoing internal rotation about the N-Sn-N axes with lifetimes of the order of 0.5 s at moderately lowered temperature.

Keywords

MAGIC ANGLE SPINNING