Stereochemisty of 3,3-disubstituted 2-methoxy-1,2-oxazolidines
Authors:
- Remir G. KostyanovskyRKRemir G. Kostyanovsky
- Volker SchurigVSVolker Schurig
- Konstantin A. LyssenkoKLKonstantin A. Lyssenko
- Oliver TrappOTOliver Trapp
- Gulnara K. KadorkinaGKGulnara K. Kadorkina
- Vasily R. KostyanovskyVKVasily R. Kostyanovsky
- Boris B. AverkievBABoris B. Averkiev
- 1 January 2004
- journal article
- Published by OOO Zhurnal "Mendeleevskie Soobshcheniya" in Mendeleev Communications
- Vol. 14 (6) , 306-309
Abstract
The conformations and anomeric effects for 1–3 in solution and for 3 in the solid state were investigated. The resolution of 1 by enantioselective gas chromatography was carried out and activation parameters of inversion in 1 were determined. The asymmetric transformation of the title compounds in an optically active solvent is discussed.Keywords
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