Atomic nature of theLII,IIIwhite lines in Ca, Sc, and Ti metals as revealed by resonant photoemission

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Abstract
The valence-band photoemission of Ca, Sc, and Ti is shown to be resonantly enhanced for excitation energies in the LII,III white lines. This favors an atomic approach to the line shape and intensity ratio of the white lines over the band-structure approach, which was recently found to be at variance with experiments.

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