Temperature Sensitive Gels as Size Selective Absorbants
Authors:
- 1 February 1987
- journal article
- research article
- Published by Taylor & Francis in Separation Science and Technology
- Vol. 22 (2-3) , 911-919
Abstract
We have used crosslinked polymer gels as extraction solvents for aqueous solutions. The gels swell to many times their dry weight by absorbing water and low molecular weight solutes, but excluding proteins and other high molecular weight solutes. The swollen gel is removed by filtration. When it is slightly warmed, it collapses, releasing most of the absorbed material. This sudden change of swelling with temperature occurs because the gel is near a critical point. After the gel is separated from the desorbed water by filtration, it is cooled and then can be reused.Keywords
This publication has 9 references indexed in Scilit:
- Volume phase transition in a nonionic gelThe Journal of Chemical Physics, 1984
- A method for concentrating dilute solutions of macromoleculesAnalytical Biochemistry, 1983
- Phase transition in swollen gelsPolymer Bulletin, 1982
- Analytical techniques for cell fractionsAnalytical Biochemistry, 1979
- Cross‐linked copolymers of N,N‐diethylacrylamide with improved mechanical propertiesJournal of Polymer Science: Polymer Symposia, 1979
- Plasma Membrane: Rapid Isolation and Exposure of the Cytoplasmic Surface by Use of Positively Charged BeadsScience, 1977
- Solution Properties of Poly(N-isopropylacrylamide)Journal of Macromolecular Science: Part A - Chemistry, 1968
- A Method for concentrating Solutes of High Molecular WeightNature, 1960
- The thermodynamic properties of aqueous solutions of polyethylene glycol, polypropylene glycol and dioxaneTransactions of the Faraday Society, 1957