Visible‐Light‐Enabled Carboxylation of Benzyl Alcohol Derivatives with CO2 Using a Palladium/Iridium Dual Catalyst
- 25 November 2021
- journal article
- research article
- Published by Wiley in ChemSusChem
- Vol. 15 (3) , e202102095
Abstract
A highly efficient carboxylation of benzyl alcohol derivatives with CO2 using a palladium/iridium dual catalyst under visible‐light irradiation was developed. A wide range of benzyl alcohol derivatives could be employed to provide benzylic carboxylic acids in moderate to high yields. Mechanistic studies indicated that the oxidative addition of benzyl alcohol derivatives was possibly the rate‐determining‐step. It was also found that a switchable site‐selective carboxylation between benzylic C−O and aryl C−Cl moieties could be achieved simply by changing the palladium catalyst.Keywords
This publication has 80 references indexed in Scilit:
- Ni-Catalyzed Direct Carboxylation of Benzyl Halides with CO2Journal of the American Chemical Society, 2013
- Palladium-Catalyzed Carboxylative Coupling of Benzyl Chlorides with Allyltributylstannane: Remarkable Effect of Palladium NanoparticlesOrganic Letters, 2012
- Carbon dioxide as a carbon source in organic transformation: carbon–carbon bond forming reactions by transition-metal catalystsChemical Communications, 2012
- Sequential Protocol for C(sp3)–H Carboxylation with CO2: Transition-Metal-Catalyzed Benzylic C–H Silylation and Fluoride-Mediated CarboxylationOrganic Letters, 2012
- Umwandlung von Kohlendioxid mit Übergangsmetall‐Homogenkatalysatoren: eine molekulare Lösung für ein globales Problem?Angewandte Chemie, 2011
- Transformation of Carbon Dioxide with Homogeneous Transition‐Metal Catalysts: A Molecular Solution to a Global Challenge?Angewandte Chemie International Edition, 2011
- Myth or Reality? Fixation of Carbon Dioxide into Complex Organic Matter under Mild ConditionsChemSusChem, 2011
- Transition-metal-catalyzed C–C bond formation through the fixation of carbon dioxideChemical Society Reviews, 2011
- Electrochemical carboxylation of benzylic carbonates: alternative method for efficient synthesis of arylacetic acidsTetrahedron, 2010
- Transformation of Carbon DioxideChemical Reviews, 2007