Biomimetic catalytic aerobic oxidation of C–sp(3)–H bonds under mild conditions using galactose oxidase model compound CuIIL
Open Access
- 28 July 2022
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Science
- Vol. 13 (33) , 9560-9568
Abstract
A biomimetic catalytic approach for the aerobic oxidation of C–sp(3)–H bonds using galactose oxidase model compound was developed. EPR showed that the CuI-radical intermediate species was critical for O2 activation.Keywords
Funding Information
- National Natural Science Foundation of China (21938001 and 21878344)
- National Key Research and Development Program of China (2020YFA0210900)
- Guangdong Provincial Pearl River Talents Program (2017BT01C102)
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