Enhanced Tetracycline Removal from Water through Synergistic Adsorption and Photodegradation Using Lignocellulose-Derived Hydrothermal Carbonation Carbon

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Abstract
Hydrothermal carbonation carbon (HTCC) is emerging as a promising material for the adsorption and photodegradation of environmental contaminants. However, the chemical and structural properties of HTCC derived from different lignocellulose biomass have obvious impacts on adsorption and photodegradation. This work employed three different lignocellulose components, including cellulose, hemicellulose, and lignin to synthesize HTCC within a hydrothermal temperature range of 210~290 °C. In comparison to HTCC derived from cellulose and hemicellulose, HTCC derived from lignin (HTCC-L) demonstrated the optimal synergistic adsorption and photodegradation ability for TC degradation, achieving a 63.5% removal efficiency within 120 min. Characterization highlighted the crucial involvement of oxygenated functional groups, especially carboxyl groups, presented on the surface of HTCC-L in TC adsorption. Moreover, the photodegradation of HTCC-L was found to follow a non-radical mechanism, characterized by the charge transformation occurring between the excited unpaired electrons of HTCC-L and TC adsorbed on its surface. This work clarified the differences in HTCC derived from different lignocellulose components on the adsorption and photodegradation of organic pollutants, and provided a novel perspective on the application of HTCC in water treatment.
Funding Information
  • National Key Research and Development Program of China (2022YFC3203701, HIT-SE-01, HC202246)
  • Heilongjiang Touyan Innovation Team Program (2022YFC3203701, HIT-SE-01, HC202246)
  • Open Project of State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology (2022YFC3203701, HIT-SE-01, HC202246)

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