Sustainable Cooling in Warm Climates: Thermodynamic Optimisation of a LiBr–H₂O Absorption Refrigeration System with Heat Recovery

This study presents a comprehensive thermodynamic simulation and parametric analysis of a single-effect lithium bromide–water (LiBr–H₂O) vapour absorption refrigeration system (VARS) to assess the influence of key operating parameters on its performance, which is primarily measured by the coefficient of performance. The thermodynamic properties of the LiBr–H₂O solution are assessed using P-T-x diagrams to establish the operational limits of the cycle for given constraints, such as the absorber and the generator temperatures and the cycle’s operating pressures. The analysis includes the effects of generator temperature ($T_{gen}$), evaporator pressure ($P_{evap}$), and solution heat effectiveness ($\eta$) on the cycle performance. Additionally, exergy analyses of the cycle’s major components are performed. Simulation results demonstrate that $T_{gen}$ is the most dominant parameter that increases the COP non-linearly from 0.35 at 85 °C to 0.73 at 110 °C (for $\eta$ = 0.5, $T_{cond}$ = 40 °C), while the circulation ratio decreases sharply. Moreover, higher evaporator pressure positively influences the COP; for instance, increasing the evaporator pressure from 0.8 kPa to 1.2 kPa raised the COP from 0.71 to 0.76. This is directly correlated with the increased concentration difference between the strong and weak solutions. The heat recovery effectiveness proved vital for energy optimisation: increasing the recovery effectiveness from 0.5 to 0.9 improved the COP from approximately 0.72 to 0.82 at a fixed $T_{gen}$ of 100 °C. Absorber temperatures limit the minimum operating temperatures of the generator for the vapour production of the refrigerant (water). Moreover, the higher condenser/absorber temperatures significantly deteriorate the performance of the cycle; for instance, raising the operating temperature of the condenser/absorber from 40 °C to 45 °C results in the COP value dropping by up to 35% at a generator operating temperature of nearly 100 °C. Among all cycle components, the generator exhibits the highest exergy loss, especially at lower generator temperatures. These findings provide essential optimisation strategies for designing and operating solar or waste heat-driven LiBr–H₂O VARS units efficiently.